With the upgrading of consumption, the existing carbon-based anode materials are facing the major challenges of high preparation cost and low initial Coulomb efficiency. The fast-growing and developed sieve tube network is an inspiration to transform cattail phloem tissue (CPT) into a high-performance carbon-based anode for lithium-ion battery. In this study, porous carbon materials from CPT with abundant microchannel and nanochannel were prepared by a top-down strategy combined with an indispensable passivation process. The sidewall and end of the sieve tube are fully covered by a large number of pore structures and various supporting cells, thus ensuring the stiffness and tensile strength of phloem tissue. And benefiting from the neoteric hierarchical porous structure without Li+ trapping sites, the cells with CPT anode showed high electrochemical performance. For the passivated CPT electrode, the reversible capacity increased to 321.6 mAh/g, and the initial Coulomb efficiency was 1.47 times higher than that of the passivated CPT electrode. The CPT exhibits excellent rate performance under high current, which indicates that the abundant pore structure on the surface of the sieve tube is an effective measure to improve ion diffusion. Besides, the generation mechanism of high-performance CPT is analyzed through microstructure characterization. The improvement of electrochemical performance of CPT in this work has provided a clear strategy for the application of resource-rich natural biomass to electrochemical products.
| Published in | Journal of Electrical and Electronic Engineering (Volume 9, Issue 5) |
| DOI | 10.11648/j.jeee.20210905.12 |
| Page(s) | 153-160 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Phloem Tissue Carbon, Porous Anode, Lithium-Ion Battery, Biomass Carbon
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APA Style
Yunlong Liao, Jiahua Hu, Zhuang Sun, Wei Zhang, Xiaomeng Zhou, et al. (2021). Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries. Journal of Electrical and Electronic Engineering, 9(5), 153-160. https://doi.org/10.11648/j.jeee.20210905.12
ACS Style
Yunlong Liao; Jiahua Hu; Zhuang Sun; Wei Zhang; Xiaomeng Zhou, et al. Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries. J. Electr. Electron. Eng. 2021, 9(5), 153-160. doi: 10.11648/j.jeee.20210905.12
AMA Style
Yunlong Liao, Jiahua Hu, Zhuang Sun, Wei Zhang, Xiaomeng Zhou, et al. Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries. J Electr Electron Eng. 2021;9(5):153-160. doi: 10.11648/j.jeee.20210905.12
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Download@article{10.11648/j.jeee.20210905.12,
author = {Yunlong Liao and Jiahua Hu and Zhuang Sun and Wei Zhang and Xiaomeng Zhou and Haijun Zhang},
title = {Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries},
journal = {Journal of Electrical and Electronic Engineering},
volume = {9},
number = {5},
pages = {153-160},
doi = {10.11648/j.jeee.20210905.12},
url = {https://doi.org/10.11648/j.jeee.20210905.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeee.20210905.12},
abstract = {With the upgrading of consumption, the existing carbon-based anode materials are facing the major challenges of high preparation cost and low initial Coulomb efficiency. The fast-growing and developed sieve tube network is an inspiration to transform cattail phloem tissue (CPT) into a high-performance carbon-based anode for lithium-ion battery. In this study, porous carbon materials from CPT with abundant microchannel and nanochannel were prepared by a top-down strategy combined with an indispensable passivation process. The sidewall and end of the sieve tube are fully covered by a large number of pore structures and various supporting cells, thus ensuring the stiffness and tensile strength of phloem tissue. And benefiting from the neoteric hierarchical porous structure without Li+ trapping sites, the cells with CPT anode showed high electrochemical performance. For the passivated CPT electrode, the reversible capacity increased to 321.6 mAh/g, and the initial Coulomb efficiency was 1.47 times higher than that of the passivated CPT electrode. The CPT exhibits excellent rate performance under high current, which indicates that the abundant pore structure on the surface of the sieve tube is an effective measure to improve ion diffusion. Besides, the generation mechanism of high-performance CPT is analyzed through microstructure characterization. The improvement of electrochemical performance of CPT in this work has provided a clear strategy for the application of resource-rich natural biomass to electrochemical products.},
year = {2021}
}
TY - JOUR T1 - Hierarchical Microchannel Carbons Derived from Biological Phloem Tissues as High-Performance Anode for Lithium-Ion Batteries AU - Yunlong Liao AU - Jiahua Hu AU - Zhuang Sun AU - Wei Zhang AU - Xiaomeng Zhou AU - Haijun Zhang Y1 - 2021/09/15 PY - 2021 N1 - https://doi.org/10.11648/j.jeee.20210905.12 DO - 10.11648/j.jeee.20210905.12 T2 - Journal of Electrical and Electronic Engineering JF - Journal of Electrical and Electronic Engineering JO - Journal of Electrical and Electronic Engineering SP - 153 EP - 160 PB - Science Publishing Group SN - 2329-1605 UR - https://doi.org/10.11648/j.jeee.20210905.12 AB - With the upgrading of consumption, the existing carbon-based anode materials are facing the major challenges of high preparation cost and low initial Coulomb efficiency. The fast-growing and developed sieve tube network is an inspiration to transform cattail phloem tissue (CPT) into a high-performance carbon-based anode for lithium-ion battery. In this study, porous carbon materials from CPT with abundant microchannel and nanochannel were prepared by a top-down strategy combined with an indispensable passivation process. The sidewall and end of the sieve tube are fully covered by a large number of pore structures and various supporting cells, thus ensuring the stiffness and tensile strength of phloem tissue. And benefiting from the neoteric hierarchical porous structure without Li+ trapping sites, the cells with CPT anode showed high electrochemical performance. For the passivated CPT electrode, the reversible capacity increased to 321.6 mAh/g, and the initial Coulomb efficiency was 1.47 times higher than that of the passivated CPT electrode. The CPT exhibits excellent rate performance under high current, which indicates that the abundant pore structure on the surface of the sieve tube is an effective measure to improve ion diffusion. Besides, the generation mechanism of high-performance CPT is analyzed through microstructure characterization. The improvement of electrochemical performance of CPT in this work has provided a clear strategy for the application of resource-rich natural biomass to electrochemical products. VL - 9 IS - 5 ER -
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